Hypervalent iodine chemistry : preparation, structure, and synthetic applications of polyvalent iodine compounds /
Hypervalent Iodine Chemistry is the first comprehensive text covering all of the main aspects of the chemistry of organic and inorganic polyvalent iodine compounds, including applications in chemical research, medicine, and industry. Providing a comprehensive overview of the preparation, properties,...
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Full text (MCPHS users only) |
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| Format: | Electronic eBook |
| Language: | English |
| Published: |
Chichester, West Sussex :
John Wiley & Sons, Inc.,
2013
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| Subjects: | |
| Local Note: | ProQuest Ebook Central |
MARC
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| 100 | 1 | |a Zhdankin, Viktor V., |d 1956- | |
| 245 | 1 | 0 | |a Hypervalent iodine chemistry : |b preparation, structure, and synthetic applications of polyvalent iodine compounds / |c Viktor V. Zhdankin. |
| 264 | 1 | |a Chichester, West Sussex : |b John Wiley & Sons, Inc., |c 2013. | |
| 300 | |a 1 online resource (viii, 468 pages) : |b illustrations | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 504 | |a Includes bibliographical references and index. | ||
| 505 | 0 | |a Hypervalent Iodine Chemistry; Contents; Preface; 1 Introduction and General Overview of Polyvalent Iodine Compounds; 1.1 Introduction; 1.2 Classification and Nomenclature of Polyvalent Iodine Compounds; 1.3 Hypervalent Bonding; 1.4 General Structural Features; 1.4.1 Experimental Structural Studies; 1.4.2 Computational Studies; 1.5 General Principles of Reactivity; 1.5.1 Ligand Exchange and Reductive Elimination; 1.5.2 Radical Reactions; 1.5.3 Single-Electron Transfer (SET) Reactions; References; 2 Preparation, Structure and Properties of Polyvalent Iodine Compounds; 2.1 Iodine(III) Compounds | |
| 505 | 8 | |a 2.1.1 Inorganic Iodine(III) Derivatives2.1.2 Organoiodine(III) Fluorides; 2.1.3 Organoiodine(III) Chlorides; 2.1.4 Organo-Iodosyl Compounds; 2.1.5 Organoiodine(III) Carboxylates; 2.1.6 [Hydroxy(Organosulfonyloxy)Iodo]Arenes; 2.1.7 Organoiodine(III) Derivatives of Strong Acids; 2.1.8 Iodine(III) Heterocycles; 2.1.9 Iodonium Salts; 2.1.10 Iodonium Ylides; 2.1.11 Iodine(III) Species with Three Carbon Ligands; 2.1.12 Iodine(III) Species with I-N Bonds; 2.2 Iodine(V) Compounds; 2.2.1 Inorganic Iodine(V) Derivatives; 2.2.2 Noncyclic and Pseudocyclic Iodylarenes; 2.2.3 Iodine(V) Heterocycles | |
| 505 | 8 | |a 2.2.4 Organoiodine(V) Fluorides2.3 Iodine(VII) Compounds; References; 3 Hypervalent Iodine Reagents in Organic Synthesis; 3.1 Reactions of Iodine(III) Compounds; 3.1.1 Fluorinations; 3.1.2 Chlorinations; 3.1.3 Brominations; 3.1.4 Iodinations; 3.1.5 Oxidation of Alcohols; 3.1.6 Oxidative Functionalization of Carbonyl Compounds; 3.1.7 Oxidative Functionalization of Silyl Enol Ethers; 3.1.8 Oxidation of Alkenes and Alkynes; 3.1.9 Oxidations at the Benzylic or Allylic Position; 3.1.10 Oxidative Functionalization of Aromatic Compounds | |
| 505 | 8 | |a 3.1.11 Oxidative Dearomatization of Phenols and Related Substrates3.1.12 Oxidative Coupling of Aromatic Substrates; 3.1.13 Oxidative Cationic Cyclizations, Rearrangements and Fragmentations; 3.1.14 Oxidations at Nitrogen, Sulfur and other Heteroatoms; 3.1.15 Azidations; 3.1.16 Aminations; 3.1.17 Thiocyanations and Arylselenations; 3.1.18 Radical Fragmentations, Rearrangements and Cyclizations; 3.1.19 Reactions via Alkyliodine(III) Intermediates; 3.1.20 Transition Metal Catalyzed Oxidations; 3.1.21 Transition Metal Catalyzed Aziridinations and Amidations | |
| 505 | 8 | |a 3.1.22 Reactions of Iodonium Salts and C-Substituted Benziodoxoles3.1.23 Reactions of Iodonium Ylides; 3.2 Synthetic Applications of Iodine(V) Compounds; 3.2.1 Noncyclic and Pseudocyclic Iodylarenes; 3.2.2 2-Iodoxybenzoic Acid (IBX); 3.2.3 Dess-Martin Periodinane (DMP); 3.2.4 Inorganic Iodine(V) Reagents; 3.3 Synthetic Applications of Iodine(VII) Compounds; References; 4 Hypervalent Iodine Catalysis; 4.1 Catalytic Cycles Based on Iodine(III) Species; 4.1.1 Oxidative a-Functionalization of Carbonyl Compounds; 4.1.2 Oxidative Functionalization of Alkenes and Alkynes | |
| 520 | |a Hypervalent Iodine Chemistry is the first comprehensive text covering all of the main aspects of the chemistry of organic and inorganic polyvalent iodine compounds, including applications in chemical research, medicine, and industry. Providing a comprehensive overview of the preparation, properties, and synthetic applications of this important class of reagents, the text is presented in the following way: -The introductory chapter provides a historical background and describes the general classification of iodine compounds, nomenclature, hypervalent bonding, structural features, and the principles of reactivity of polyvalent iodine compounds.-Chapter 2 gives a detailed description of the preparative methods and structural features of all known classes of organic and inorganic derivatives of polyvalent iodine.-Chapter 3, the key chapter of the book, deals with the many applications of hypervalent iodine reagents in organic synthesis.-Chapter 4 describes the most recent achievements in hypervalent iodine catalysis.-Chapter 5 deals with recyclable polymer-supported and nonpolymeric hypervalent iodine reagents.-Chapter 6 covers the "green" reactions of hypervalent iodine reagents under solvent-free conditions or in aqueous solutions.-The final chapter provides an overview of the important practical applications of polyvalent iodine compounds in medicine and industry. This book is aimed at all chemists interested in iodine compounds, including academic and industrial researchers in inorganic, organic, physical, medicinal, and biological chemistry. It will be particularly useful to synthetic organic and inorganic chemists, including graduate and advanced undergraduate students. It comprehensively covers the green chemistry aspects of hypervalent iodine chemistry, making it especially useful for industrial chemists. | ||
| 588 | 0 | |a Print version record. | |
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Iodine compounds. | |
| 650 | 0 | |a Organoiodine compounds. | |
| 650 | 0 | |a Hypervalence (Theoretical chemistry) | |
| 650 | 2 | |a Iodine Compounds | |
| 758 | |i has work: |a Hypervalent iodine chemistry (Text) |1 https://id.oclc.org/worldcat/entity/E39PCGphdv74vVKHkCWRbXTXHP |4 https://id.oclc.org/worldcat/ontology/hasWork | ||
| 776 | 0 | 8 | |i Print record: |a Zhdankin, Viktor V., 1956- |t Hypervalent iodine chemistry. |d Chichester, West Sussex : John Wiley & Sons, Inc., 2014 |z 9781118341032 |w (DLC) 2013020439 |w (OCoLC)847600792 |
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