Phosphorus(III) ligands in homogeneous catalysis : design and synthesis /
"Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the ackn...
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| Language: | English |
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Chichester, West Sussex, United Kingdom :
John Wiley & Sons, Ltd.,
2012
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| Local Note: | ProQuest Ebook Central |
MARC
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| 100 | 1 | |a Kamer, Paul. | |
| 245 | 1 | 0 | |a Phosphorus(III) ligands in homogeneous catalysis : |b design and synthesis / |c edited by Paul Kamer & Piet W.N.M. van Leeuwen. |
| 260 | |a Chichester, West Sussex, United Kingdom : |b John Wiley & Sons, Ltd., |c 2012. | ||
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 504 | |a Includes bibliographical references and index. | ||
| 505 | 0 | |a Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis; Contents; List of Contributors; Preface; 1 Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design; 1.1 Introduction; 1.2 Properties of phosphorus ligands; 1.2.1 Electronic ligand parameters; 1.2.2 Steric ligand parameters; 1.2.3 Bite angle effects; 1.2.4 Molecular electrostatic potential (MESP) approach; 1.3 Asymmetric ligands; 1.4 Rational ligand design in nickel-catalysed hydrocyanation; 1.4.1 Introduction; 1.4.2 Mechanistic insights; 1.4.3 Rational design; 1.5 Conclusions; References. | |
| 520 | |a "Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals. This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation. Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands. Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry"-- |c Provided by publisher. | ||
| 588 | 0 | |a Print version record and CIP data provided by publisher. | |
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Phosphorus compounds. | |
| 650 | 0 | |a Ligands. | |
| 650 | 0 | |a Catalysis. | |
| 700 | 1 | |a Leeuwen, P. W. N. M. van |q (Piet W. N. M.) |1 https://id.oclc.org/worldcat/entity/E39PBJbRggkH8kvhQJg6q6jV4q | |
| 776 | 0 | 8 | |i Print version: |a Kamer, Paul. |t Phosphorus(III) ligands in homogeneous catalysis. |d Hoboken, N.J. : Wiley, 2012 |z 9780470666272 |w (DLC) 2012000246 |
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| 880 | 8 | |6 505-00/(S |a 10.5.2 Synthesis of PhAk-Ox -- 10.6 Acknowledgments -- References -- 11 Phosphaalkynes -- 11.1 Introduction -- 11.2 General experimental -- 11.3 Preparation of PCtBu -- 11.3.1 Tris(trimethylsilyl)phosphine, P(SiMe3)3 -- 11.3.2 tert-butylphosphaalkene, Me3SiP = C(OSiMe3)tBu (systematic name [2,2-dimethyl-1-(trimethylsiloxy)propylidene]-(trimethylsilyl) phosphine) -- 11.3.3 tert-butylphosphaalkyne, systematic name (2,2-dimethylpropylidyne)phosphine -- tBuC≡P -- 11.4 Adamanylphosphaalkyne, AdC≡P -- 11.4.1 Adamant-1-yl(trimethylsiloxy)methylidene (trimethylsilyl) phosphine -- 11.4.2 (Adamant-1-ylmethylidyne)phosphine -- 11.5 Mesitylphosphaalkyne, MesC≡P -- 11.5.1 Preparation of potassium bis(trimethylsilyl)phosphide {KP(SiMe3)2} -- 11.5.2 Mesityl(trimethylsiloxy)methylene trimethylsilylphosphine -- 11.5.3 Mesitylphosphaalkyne -- 11.6 Phospholide anions -- 11.6.1 Preparation of Cp2Zr(PCtBu)2 -- 11.6.2 Preparation of ClP(PCtBu)2 -- 11.6.3 Preparation of the triphospholide anion and derivation to give the triphenylstannylphosphole -- 11.6.4 Preparation of Cl3P3(CtBu)2 -- 11.6.5 Preparation of the triphospholide anion -- 11.7 1,3,5-Triphosphabenzene -- 11.7.1 Preparation of Cl3VNtBu -- 11.7.2 Preparation of 1,3,5-triphospabenzene -- P3(CtBu)3 -- References -- 12 P-chiral Ligands -- 12.1 Introduction -- 12.2 Designing P-chiral ligands using alcohols as chiral auxiliaries -- 12.3 Designing P-chiral ligands using amino alcohols as chiral auxiliaries -- 12.3.1 Synthesis starting from tricoordinated 1,3,2-oxazaphospholidines -- 12.3.2 Synthesis starting from tetracoordinated 1,3,2-oxazaphospholidines -- 12.3.3 Synthesis starting from 1,3,2-oxazaphospholidine borane complexes -- 12.4 Designing of P-chiral ligands using amines as chiral auxiliaries -- 12.4.1 Sparteine as chiral auxiliary -- 12.4.2 α-Arylethylamines as chiral auxiliaries -- 12.5 Conclusion. | |
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